SUSTAINABLE LIGNIN EXTRACTED FROM BANANA STEM BIOMASS AS A FUNCTIONAL UV-BLOCKING INGREDIENT IN SUNSCREEN
DOI:
https://doi.org/10.36526/jc.v8i1.7005Keywords:
Lignin-based sunscreen, Banana stem biomass, Deep Eutectic Solvent (DES), UV protection, Sustainable cosmeticsAbstract
Banana stem biomass, an abundant agricultural by-product, contains significant lignin content and offers strong potential for valorization through green extraction technologies. In this study, lignin was extracted using an environmentally friendly Deep Eutectic Solvent (DES) composed of choline chloride and citric acid and subsequently incorporated into sunscreen cream formulations at concentrations of 2%, 3%, and 4%. The photoprotective performance of the formulations was evaluated through UV–Vis spectrophotometry, while pH measurements ensured compliance with SNI 16-4399-1996. FTIR analysis was conducted to compare the structural characteristics of DES-extracted lignin with those obtained using conventional NaOH extraction. The results revealed that all lignin-based formulations effectively absorbed UVA (320–400 nm) and UVB (280–320 nm) radiation, with UV absorbance increasing alongside lignin concentration; the 4% formulation showed the strongest UV-blocking capability. All samples maintained a skin-compatible pH of approximately 6. FTIR spectra further indicated that DES-extracted lignin preserved aromatic structures more effectively than NaOH-extracted lignin. Overall, the findings highlight the potential of banana stem-derived lignin as a natural UV-blocking and antioxidant ingredient for eco-friendly sunscreen products, supporting the advancement of sustainable cosmetic innovation.
References
Badan Pusat Statistik (BPS). (2024). Statistik Indonesia 2024: Statistical Yearbook of Indonesia 2024. Jakarta: BPS-Statistics Indonesia. Volume 52. Katalog/Catalogue: 1101001, ISSN: 0126-2912
Bhatia, S. K., Jagtap, S. S., Bedekar, A. A., Bhatia, R. K., Patel, A. K., Pant, D., Rajesh Banu, J., Rao, C. V, Kim, Y.-G., & Yang, Y.-H. (2020). Recent developments in pretreatment technologies on lignocellulosic biomass: Effect of key parameters, technological improvements, and challenges. Bioresource Technology, 300, 122724. https://doi.org/https://doi.org/10.1016/j.biortech.2019.122724
Chen, Z., Ragauskas, A., & Wan, C. (2020). Lignin extraction and upgrading using deep eutectic solvents. Industrial Crops and Products, 147, 112241. https://doi.org/https://doi.org/10.1016/j.indcrop.2020.112241
Faiz Norrrahim, M. N., Ahmad Farid, M. A., Lawal, A. A., Tengku Yasim-Anuar, T. A., Samsudin, M. H., & Zulkifli, A. A. (2022). Emerging technologies for value-added use of oil palm biomass. Environmental Science: Advances, 1(3), 259–275. https://doi.org/10.1039/D2VA00029F
G S, V., Archana, P. T., & K, A. (2025). Sustainable bioethanol synthesis from Queen sago seed shells via sequential acid hydrolysis and fermentation. Materials Research Express, 12(8), 085502. https://doi.org/10.1088/2053-1591/adf695
Lee, S. C., Tran, T. M. T., Choi, J. W., & Won, K. (2019). Lignin for white natural sunscreens. International Journal of Biological Macromolecules, 122, 549–554. https://doi.org/https://doi.org/10.1016/j.ijbiomac.2018.10.184
Li, C., Huang, C., Zhao, Y., Zheng, C., Su, H., Zhang, L., Luo, W., Zhao, H., Wang, S., & Huang, L.-J. (2021). Effect of Choline-Based Deep Eutectic Solvent Pretreatment on the Structure of Cellulose and Lignin in Bagasse. Processes, 9(2). https://doi.org/10.3390/pr9020384
Muliari, M., Zulfahmi, I., Akmal, Y., Karja, N. W. K., Nisa, C., & Sumon, K. A. (2019). Effects of palm oil mill effluent on reproductive hormone of female Nile Tilapia, Oreochromis niloticus (Linnaeus 1758). Advances in Animal and Veterinary Sciences, 7(11), 1035–1041. https://doi.org/10.17582/journal.aavs/2019/7.11.1035.1041
Rokhim, D. A., Adid, A. W., Tyas, F. K., Ciptawati, E., & Asrori, M. R. (2022). Utilization of Banana Stem Waste Extracts Assisted by Electrode of Cu/Mg as an Environmentally Friendly Electricity Producer. Orbital: The Electronic Journal of Chemistry, 14(1), 40–44. https://periodicos.ufms.br/index.php/orbital/article/view/15500
Sander, M., Sander, M., Burbidge, T., & Beecker, J. (2020). The efficacy and safety of sunscreen use for the prevention of skin cancer. Canadian Medical Association Journal, 192(50), E1802. https://doi.org/10.1503/cmaj.201085
Usmani, Z., Sharma, M., Gupta, P., Karpichev, Y., Gathergood, N., Bhat, R., & Gupta, V. K. (2020). Ionic liquid based pretreatment of lignocellulosic biomass for enhanced bioconversion. Bioresource Technology, 304, 123003. https://doi.org/https://doi.org/10.1016/j.biortech.2020.123003
Wang, W., & Lee, D.-J. (2021). Lignocellulosic biomass pretreatment by deep eutectic solvents on lignin extraction and saccharification enhancement: A review. Bioresource Technology, 339, 125587. https://doi.org/https://doi.org/10.1016/j.biortech.2021.125587
Yana, S., Nizar, M., Irhamni, & Mulyati, D. (2022). Biomass waste as a renewable energy in developing bio-based economies in Indonesia: A review. Renewable and Sustainable Energy Reviews, 160, 112268. https://doi.org/https://doi.org/10.1016/j.rser.2022.112268
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Copyright (c) 2026 Sheryl Ayesha, Nanda Aurelia Salsabila S, Teguh Pambudi, Hasti Asfarina, Hilman Imadul Umam, Fajar Amelia Rachmawati Putri

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